Tuning spin-crossover transition temperatures in non-symmetrical homoleptic meridional/facial [Fe(didentate)<sub>3</sub>]<sup>2+</sup>complexes: what for and who cares about it?

نویسندگان

چکیده

The spin transition temperatures of [Fe(didentate)3]2+in acetonitrile (didentate = 2-X-benzimidazole) can be stepwise decreased by 40 K along the series X pyrazine &gt; pyridine pyrimidine.

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ژورنال

عنوان ژورنال: Dalton Transactions

سال: 2021

ISSN: ['1477-9234', '1477-9226']

DOI: https://doi.org/10.1039/d0dt03828h